This research has carried out assessment on a framework of collaborative learning which gets support from the Superstar mobile library application, in a course about university digital library. We have employed a design that is pretest-posttest for one single group. Fifty-one new students who just enter the School of Arts of Zhoukou Normal University were selected through the method of cluster random sampling. One assessment form which has validity 1.00 and reliability 0.71 was utilized by us to measure the ability of people to seek information, and the lesson plans were checked through experts. The result showed that the students’ after-test marks were obviously higher than their before-test marks, t(34)=15.19, p < 0.05. Furthermore, these scores also have exceeded the 70% standard, t(34)=47.21, p < 0.05. Therefore, the combination that is made of collaborative learning and the Superstar mobile library app has enhanced the information-seeking skills of students.